Aldehydes were chemoselectively reduced to primary alcohols by using HCOONH4 as the hydrogen donor through transfer hydrogenation catalyzed by benzo[h]quinoline pincer complexes RuCl(CNNPh)(PP) at substrate to catalyst molar ratios of 2000 to 20 000. This practical reaction performed with aldehydes of commercial-grade purity in a water/toluene biphasic system afforded alcohols without the formation of condensation or amination side products.
Titolo: | Chemoselective Transfer Hydrogenation of Aldehydes with HCOONH4 Catalyzed by RuCl(CNNPh)(PP) Pincer Complexes |
Autori: | |
Data di pubblicazione: | 2016 |
Rivista: | |
Abstract: | Aldehydes were chemoselectively reduced to primary alcohols by using HCOONH4 as the hydrogen donor through transfer hydrogenation catalyzed by benzo[h]quinoline pincer complexes RuCl(CNNPh)(PP) at substrate to catalyst molar ratios of 2000 to 20 000. This practical reaction performed with aldehydes of commercial-grade purity in a water/toluene biphasic system afforded alcohols without the formation of condensation or amination side products. |
Handle: | http://hdl.handle.net/11390/1101725 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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