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EnglishAldehydes were chemoselectively reduced to primary alcohols by using HCOONH4 as the hydrogen donor through transfer hydrogenation catalyzed by benzo[h]quinoline pincer complexes RuCl(CNNPh)(PP) at substrate to catalyst molar ratios of 2000 to 20 000. This practical reaction performed with aldehydes of commercial-grade purity in a water/toluene biphasic system afforded alcohols without the formation of condensation or amination side products.
| Titolo: | Chemoselective Transfer Hydrogenation of Aldehydes with HCOONH4 Catalyzed by RuCl(CNNPh)(PP) Pincer Complexes | |
| Autori: | ||
| Data di pubblicazione: | 2016 | |
| Rivista: | ||
| Abstract: | Aldehydes were chemoselectively reduced to primary alcohols by using HCOONH4 as the hydrogen donor through transfer hydrogenation catalyzed by benzo[h]quinoline pincer complexes RuCl(CNNPh)(PP) at substrate to catalyst molar ratios of 2000 to 20 000. This practical reaction performed with aldehydes of commercial-grade purity in a water/toluene biphasic system afforded alcohols without the formation of condensation or amination side products. | |
| Handle: | http://hdl.handle.net/11390/1101725 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| Baldino_et_al-2016-ChemCatChem.pdf | Versione Editoriale (PDF) | Non pubblico | Accesso ristretto Richiedi una copia |
Utilizza questo identificativo per citare o creare un link a questo documento:
http://hdl.handle.net/11390/1101725
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