A hetero-bimetallic Pd-Ru N-Heterocyclic Dicarbene (NHDC) complex was synthesized from a Ag-Ru complex by transmetalation. The Pd-Ru system displays high catalytic activity in tandem Suzuki-Miyaura cross-coupling/transfer hydrogenation reaction of bromoaryl ketones with boronic acids in toluene and 2-propanol in the presence of KOH.

Tandem Suzuki-Miyaura/transfer hydrogenation reaction catalyzed by a Pd-Ru complex bearing an anionic dicarbene

BARATTA, Walter
2016

Abstract

A hetero-bimetallic Pd-Ru N-Heterocyclic Dicarbene (NHDC) complex was synthesized from a Ag-Ru complex by transmetalation. The Pd-Ru system displays high catalytic activity in tandem Suzuki-Miyaura cross-coupling/transfer hydrogenation reaction of bromoaryl ketones with boronic acids in toluene and 2-propanol in the presence of KOH.
File in questo prodotto:
File Dimensione Formato  
P406.pdf

non disponibili

Tipologia: Versione Editoriale (PDF)
Licenza: Non pubblico
Dimensione 1.83 MB
Formato Adobe PDF
1.83 MB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11390/1101732
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 19
  • ???jsp.display-item.citation.isi??? 20
social impact