Mechanochemical synthesis for the preparation of bimetallic catalysts is gaining increasing interest, and in recent years, some important milestones have been reached. However, the complexity of mechanochemically prepared bimetallic supported catalysts still leaves many open questions that need a systematic approach to be solved. In this work, we summarize our experience of mechanochemically milling bimetallic catalysts, introducing some key parameters that should be taken into account, particularly the thermal stability and hydrophilicity of precursor salts, and the effect of the milling order, highlighting the differences with wet synthesis methods. Finally, we will provide some suggestions on the application of the design of experiments approach to the rationalization of the milling procedure for the preparation of supported bimetallic catalysts.
Relevant Parameters for the Mechanochemical Synthesis of Bimetallic Supported Catalysts
Danielis M.;Braga A.;Trovarelli A.;Colussi S.
2023-01-01
Abstract
Mechanochemical synthesis for the preparation of bimetallic catalysts is gaining increasing interest, and in recent years, some important milestones have been reached. However, the complexity of mechanochemically prepared bimetallic supported catalysts still leaves many open questions that need a systematic approach to be solved. In this work, we summarize our experience of mechanochemically milling bimetallic catalysts, introducing some key parameters that should be taken into account, particularly the thermal stability and hydrophilicity of precursor salts, and the effect of the milling order, highlighting the differences with wet synthesis methods. Finally, we will provide some suggestions on the application of the design of experiments approach to the rationalization of the milling procedure for the preparation of supported bimetallic catalysts.File | Dimensione | Formato | |
---|---|---|---|
crystals-13-01685.pdf
accesso aperto
Tipologia:
Versione Editoriale (PDF)
Licenza:
Creative commons
Dimensione
3.27 MB
Formato
Adobe PDF
|
3.27 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.