CINECA IRIS Institutional Research Information System
IRIS è la piattaforma adottata dall’Università degli Studi di Udine per gestire l’archivio aperto dei prodotti della ricerca. L’archivio contiene articoli, contributi in volume, monografie, interventi pubblicati in atti di convegno, Tesi di dottorato e altri materiali.
EnglishStyrene, 2-methacryloxyethylsulfonic acid and methylenebisacrylamide are copolymerized in the presence of dimethylformamide under gamma-irradiation at room temperature to give potentially amphiphilic, microporous resins. The molar fraction of methylenebisacrylamide (the cross-linker) ranges from 1 to 6 mol%. The obtained resins, after grinding and sieving, are treated with solutions of Pd(AcO)(2) and the ion-exchanged polymers are then treated with NaBH4 in ethanol. The metal content in the materials ranges from 2.1% to 2.4% (w/w). X-ray microprobe analysis shows that Pd(0) is homogeneously dispersed throughout the particles of the polymeric materials. The polymer chain concentration and its distribution in the swollen macromolecular networks are assessed by means of Inverse Steric Exclusion Chromatography (ISEC). In spite of the higher molar proportion of styrene repeating units, the Pd(0)-resin composites swell comparably in water and tetrahydrofurane, Their amphiphilic character is the result of the different swelling properties of the hydrophilic and hydrophobic domains.
Metal palladium supported on amphiphilic microporous synthetic organic supports. Part I. Material preparation and textural characterization / Zecca M; Kralik M; Boaro M; Palma G; Lora S; Zancato M; Corain; B. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - 129:1(1998), pp. 27-34.
| Titolo: | Metal palladium supported on amphiphilic microporous synthetic organic supports. Part I. Material preparation and textural characterization |
| Autori: | |
| Data di pubblicazione: | 1998 |
| Rivista: | |
| Citazione: | Metal palladium supported on amphiphilic microporous synthetic organic supports. Part I. Material preparation and textural characterization / Zecca M; Kralik M; Boaro M; Palma G; Lora S; Zancato M; Corain; B. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - 129:1(1998), pp. 27-34. |
| Abstract: | Styrene, 2-methacryloxyethylsulfonic acid and methylenebisacrylamide are copolymerized in the presence of dimethylformamide under gamma-irradiation at room temperature to give potentially amphiphilic, microporous resins. The molar fraction of methylenebisacrylamide (the cross-linker) ranges from 1 to 6 mol%. The obtained resins, after grinding and sieving, are treated with solutions of Pd(AcO)(2) and the ion-exchanged polymers are then treated with NaBH4 in ethanol. The metal content in the materials ranges from 2.1% to 2.4% (w/w). X-ray microprobe analysis shows that Pd(0) is homogeneously dispersed throughout the particles of the polymeric materials. The polymer chain concentration and its distribution in the swollen macromolecular networks are assessed by means of Inverse Steric Exclusion Chromatography (ISEC). In spite of the higher molar proportion of styrene repeating units, the Pd(0)-resin composites swell comparably in water and tetrahydrofurane, Their amphiphilic character is the result of the different swelling properties of the hydrophilic and hydrophobic domains. |
| Handle: | http://hdl.handle.net/11390/673587 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| Metal palladium supported on amphiphilic microporous synthetic organic supports.Part I Materials preparation and textural characterization.pdf | Altro materiale allegato | Non pubblico | Accesso ristretto Richiedi una copia |
http://hdl.handle.net/11390/673587
Copyright © 2021