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EnglishThe extension of the N-permethylation reaction of amines to aromatic amines with strong electron withdrawing substituets in o- and p-positions is reported. The reaction could be extended to the syntheses of N-permethyl-derivatives of amines of the type CH3-nDn by the use of formaldehyde, dideuteroformaldehyde, sodium borodeuteride and -hydride. Label conservation in the reaction is complete. The MS of the labelled compounds revealed extensive label exchange in the ionization chamber.
| Titolo: | New N-Permethylations and Introduction of Deuterium Labelled Methyl Groups into Primary and Secondary Amines |
| Autori: | |
| Data di pubblicazione: | 1987 |
| Rivista: | |
| Abstract: | The extension of the N-permethylation reaction of amines to aromatic amines with strong electron withdrawing substituets in o- and p-positions is reported. The reaction could be extended to the syntheses of N-permethyl-derivatives of amines of the type CH3-nDn by the use of formaldehyde, dideuteroformaldehyde, sodium borodeuteride and -hydride. Label conservation in the reaction is complete. The MS of the labelled compounds revealed extensive label exchange in the ionization chamber. |
| Handle: | http://hdl.handle.net/11390/680892 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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