CINECA IRIS Institutional Research Information System
IRIS è la piattaforma adottata dall’Università degli Studi di Udine per gestire l’archivio aperto dei prodotti della ricerca. L’archivio contiene articoli, contributi in volume, monografie, interventi pubblicati in atti di convegno, Tesi di dottorato e altri materiali.
EnglishThe extension of the N-permethylation reaction of amines to aromatic amines with strong electron withdrawing substituets in o- and p-positions is reported. The reaction could be extended to the syntheses of N-permethyl-derivatives of amines of the type CH3-nDn by the use of formaldehyde, dideuteroformaldehyde, sodium borodeuteride and -hydride. Label conservation in the reaction is complete. The MS of the labelled compounds revealed extensive label exchange in the ionization chamber.
| Titolo: | New N-Permethylations and Introduction of Deuterium Labelled Methyl Groups into Primary and Secondary Amines |
| Autori: | |
| Data di pubblicazione: | 1987 |
| Rivista: | |
| Abstract: | The extension of the N-permethylation reaction of amines to aromatic amines with strong electron withdrawing substituets in o- and p-positions is reported. The reaction could be extended to the syntheses of N-permethyl-derivatives of amines of the type CH3-nDn by the use of formaldehyde, dideuteroformaldehyde, sodium borodeuteride and -hydride. Label conservation in the reaction is complete. The MS of the labelled compounds revealed extensive label exchange in the ionization chamber. |
| Handle: | http://hdl.handle.net/11390/680892 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
http://hdl.handle.net/11390/680892
Copyright © 2021