A single reagent, i.e. n-butyl nitrite, can be used to oxidize an aromatic amine, or the corresponding N-methylene derivative, to a diazo compound followed by its subsequent reduction to hydrocarbon in a single batch. Alternatively, a chloro derivative can be obtained if carbon tetrachloride is used as the solvent. The reactions appear to be general and complete product identification was accomplished.
Hydrocarbons and Chloroaromatics from Anilines and n-Butyl Nitrite
VERARDO, Giancarlo;STRAZZOLINI, Paolo
1995-01-01
Abstract
A single reagent, i.e. n-butyl nitrite, can be used to oxidize an aromatic amine, or the corresponding N-methylene derivative, to a diazo compound followed by its subsequent reduction to hydrocarbon in a single batch. Alternatively, a chloro derivative can be obtained if carbon tetrachloride is used as the solvent. The reactions appear to be general and complete product identification was accomplished.File in questo prodotto:
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