The photochemical behaviour of benzophenoneimine and fluorenoneimine in several solvents on irradiation in the 200 - 300 (400) nm range was studied. Reduction to hydrocarbons diphenylmethane and fluorene was consistently observed, although to varying extents, with corresponding oxidation of the reactive solvents to dimers. Variable amounts of nitrogenous compounds were observed in addition to radical coupling and dimerization products. A certain amount of polymeric material accompanied all the photolyses. The product study was also extended to the photolysis in methanol of the benzophenoneimine and fluorenoneimine hydrochlorides.

Product study of the photolysis of Benzophenoneimine and fluorenoneimine

VERARDO, Giancarlo;STRAZZOLINI, Paolo;
1989-01-01

Abstract

The photochemical behaviour of benzophenoneimine and fluorenoneimine in several solvents on irradiation in the 200 - 300 (400) nm range was studied. Reduction to hydrocarbons diphenylmethane and fluorene was consistently observed, although to varying extents, with corresponding oxidation of the reactive solvents to dimers. Variable amounts of nitrogenous compounds were observed in addition to radical coupling and dimerization products. A certain amount of polymeric material accompanied all the photolyses. The product study was also extended to the photolysis in methanol of the benzophenoneimine and fluorenoneimine hydrochlorides.
File in questo prodotto:
File Dimensione Formato  
A-012.pdf

non disponibili

Tipologia: Altro materiale allegato
Licenza: Non pubblico
Dimensione 573.72 kB
Formato Adobe PDF
573.72 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11390/742248
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 1
  • ???jsp.display-item.citation.isi??? 1
social impact