The complexes [Pd(acac)(2)] 1, [Pd(hfa)(2)] 2 (hfa = hexafluoroacetylacetonate), [Pd(CF3CO2)(2)] 3 and [Pd-3(CH3CO2)(6)] 4 exhibit very different catalytic efficiency in the reaction between secondary amines and activated alkenes. Complexes 1 and 4 generally show an enhanced activity when catalytic amounts of NH4X salts (X- = low-coordinating anion) are added to the reaction mixtures. On the contrary, the activity of the perfluorurate analogues 2 and 3, which is much higher than that of 1 and 4, is generally scarcely affected by the presence of the NH4X additive. The cocatalytic effect of NH4X is comparable with that of strong acids such as CF3SO3H. The ammonium salts alone can behave as a catalyst giving an almost quantitative yield of the hydroamination product.
Addition of Secondary Amines to Activated Alkenes Promoted by Pd(II) Complexes: Use of Ammonium Salts as Cocatalysts
DEL ZOTTO, Alessandro;BARATTA, Walter;RIGO, Pierluigi
2005-01-01
Abstract
The complexes [Pd(acac)(2)] 1, [Pd(hfa)(2)] 2 (hfa = hexafluoroacetylacetonate), [Pd(CF3CO2)(2)] 3 and [Pd-3(CH3CO2)(6)] 4 exhibit very different catalytic efficiency in the reaction between secondary amines and activated alkenes. Complexes 1 and 4 generally show an enhanced activity when catalytic amounts of NH4X salts (X- = low-coordinating anion) are added to the reaction mixtures. On the contrary, the activity of the perfluorurate analogues 2 and 3, which is much higher than that of 1 and 4, is generally scarcely affected by the presence of the NH4X additive. The cocatalytic effect of NH4X is comparable with that of strong acids such as CF3SO3H. The ammonium salts alone can behave as a catalyst giving an almost quantitative yield of the hydroamination product.File | Dimensione | Formato | |
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Inorg. Chim Acta 358(2005)2749.pdf
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