We report on three Ir(III) molecular catalysts for water oxidation: 1, [Cp*Ir(ppy) Cl]; 2, [Cp*Ir(bzpy)NO(3)]; 3, [Cp*Ir(H(2)O)(3)](NO(3))(2). 2 and 3 are water-soluble and show a long-term activity ca. 2 and 3 times higher than 1. It is remarkable that 3, having the simplest structure, is the catalyst with the highest activity.

Iridium(III) molecular catalysts for water oxidation: the simpler the faster

ZUCCACCIA, Daniele;
2010-01-01

Abstract

We report on three Ir(III) molecular catalysts for water oxidation: 1, [Cp*Ir(ppy) Cl]; 2, [Cp*Ir(bzpy)NO(3)]; 3, [Cp*Ir(H(2)O)(3)](NO(3))(2). 2 and 3 are water-soluble and show a long-term activity ca. 2 and 3 times higher than 1. It is remarkable that 3, having the simplest structure, is the catalyst with the highest activity.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11390/949762
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