We report on three Ir(III) molecular catalysts for water oxidation: 1, [Cp*Ir(ppy) Cl]; 2, [Cp*Ir(bzpy)NO(3)]; 3, [Cp*Ir(H(2)O)(3)](NO(3))(2). 2 and 3 are water-soluble and show a long-term activity ca. 2 and 3 times higher than 1. It is remarkable that 3, having the simplest structure, is the catalyst with the highest activity.
Iridium(III) molecular catalysts for water oxidation: the simpler the faster
ZUCCACCIA, Daniele;
2010-01-01
Abstract
We report on three Ir(III) molecular catalysts for water oxidation: 1, [Cp*Ir(ppy) Cl]; 2, [Cp*Ir(bzpy)NO(3)]; 3, [Cp*Ir(H(2)O)(3)](NO(3))(2). 2 and 3 are water-soluble and show a long-term activity ca. 2 and 3 times higher than 1. It is remarkable that 3, having the simplest structure, is the catalyst with the highest activity.File in questo prodotto:
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