NOE and PGSE NMR experiments provide crucial information for the structural characterization of non-covalent intimate adducts in solution. The possible presence and the favorite relative orientation of the interacting units can be deduced from NOE results, while the size of the non-covalent adducts can be estimated through PGSE measurements. The complementarity of the two methodologies has been successfully used to investigate transition metal complex ion pairs and, to a lesser extent, intermolecular adducts. The main results concerning the solution structures of non-covalent inorganic adducts are reported and compared with those in the solid state and those from theoretical calculations.

Application of NOE and PGSE NMR methodologies to investigate non-covalent intimate inorganic adducts in solution

ZUCCACCIA, Daniele
2002-01-01

Abstract

NOE and PGSE NMR experiments provide crucial information for the structural characterization of non-covalent intimate adducts in solution. The possible presence and the favorite relative orientation of the interacting units can be deduced from NOE results, while the size of the non-covalent adducts can be estimated through PGSE measurements. The complementarity of the two methodologies has been successfully used to investigate transition metal complex ion pairs and, to a lesser extent, intermolecular adducts. The main results concerning the solution structures of non-covalent inorganic adducts are reported and compared with those in the solid state and those from theoretical calculations.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11390/949790
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